Suzuki coupling reactions catalyzed by Schiff base supported palladium complexes bearing the vitamin B6 cofactor

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dc.authoridZaim, Omer/0000-0002-3472-5611
dc.authoridOzcan, hafize/0000-0002-8031-6755
dc.authoridGholinejad, Mohammad/0000-0003-0209-4509
dc.authoridMousavi zadeh mobarakeh, seyed ali/0000-0002-1469-7465
dc.authoridNeshat, Abdollah/0000-0002-1424-2292
dc.authorwosidZaim, Omer/Q-7770-2019
dc.authorwosidOzcan, hafize/KJM-5364-2024
dc.authorwosidNeshat, Abdollah/AAC-8661-2022
dc.authorwosidGholinejad, Mohammad/AAC-1739-2022
dc.authorwosidMousavizadeh Mobarakeh, ali/JBJ-3152-2023
dc.contributor.authorNeshat, Abdollah
dc.contributor.authorGholinejad, Mohammad
dc.contributor.authorOzcan, Hafize
dc.contributor.authorKhosravi, Faezeh
dc.contributor.authorMobarakeh, Ali Mousavizadeh
dc.contributor.authorZaim, Omer
dc.date.accessioned2024-06-12T11:13:55Z
dc.date.available2024-06-12T11:13:55Z
dc.date.issued2021
dc.departmentTrakya Üniversitesien_US
dc.description.abstractNovel Schiff bases were synthesized by condensing aromatic amines with pyridoxal-5'-phosphate and charac-terized by using FT-IR, H-1 NMR, and C-13 NMR spectroscopic techniques. The resulting Schiff bases were utilized as bidentate ligands, coordinating via imine nitrogen and phenolate oxygen atoms, to stabilize palladium ions. Aryl substituents on imine nitrogen allowed for fine tuning of the stereoelectronic properties of the Schiff bases. The catalytic activity of the selected palladium complexes was investigated in the Suzuki cross-coupling reaction of a series of aryl halides with boronic acids in H2O/EtOH (1:1). Out of four complexes investigated in the cross-coupling reactions, Pd(L-8)(2), bearing a methoxy substituent on aryl imine, showed the highest activity at low catalyst loading. The scope of the reaction was also investigated with 26 samples.en_US
dc.description.sponsorshipscientific research project commission of Trakya University (TUBAP) [TUBAP-817]en_US
dc.description.sponsorshipFunding for this work by the scientific research project commission of Trakya University (TUBAP, TUBAP-817) is acknowledged. We thank Mr. Hassan Keshavarz, the operator of Bruker NMR spectroscopy instrument at IASBS for recording NMR and IR spectra represented in this manuscript.en_US
dc.identifier.doi10.1016/j.mcat.2021.111528
dc.identifier.issn2468-8231
dc.identifier.scopus2-s2.0-85102991180en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.mcat.2021.111528
dc.identifier.urihttps://hdl.handle.net/20.500.14551/23732
dc.identifier.volume505en_US
dc.identifier.wosWOS:000637820700006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofMolecular Catalysisen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff Baseen_US
dc.subjectPyridoxal-5-Phosphateen_US
dc.subjectHomogeneous Palladium Catalysten_US
dc.subjectCarbon-Carbon Cross Couplingen_US
dc.titleSuzuki coupling reactions catalyzed by Schiff base supported palladium complexes bearing the vitamin B6 cofactoren_US
dc.typeArticleen_US

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