Synthesis and characterization of new N-heterocyclic carbene ligands: 1,3-Bis(acetamide)imidazol-3-ium bromide and 3-(acetamide)-1-(3-aminopropy1)-1H-imidazol-3-ium bromide

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dc.authoridUluçam, Gühergül/0000-0001-6481-8483
dc.authoridOkan, Sevket Erol/0000-0002-1707-2671
dc.authorwosidUluçam, Gühergül/AAH-2862-2019
dc.authorwosidTurkyilmaz, Murat/AAK-7876-2020
dc.contributor.authorTurkyilmaz, Murat
dc.contributor.authorUlucam, Guhergul
dc.contributor.authorAktas, Saban
dc.contributor.authorOkan, S. Erol
dc.date.accessioned2024-06-12T11:03:41Z
dc.date.available2024-06-12T11:03:41Z
dc.date.issued2017
dc.departmentTrakya Üniversitesien_US
dc.description.abstractTwo new pincer type N-heterocyclic carbene ligands were synthesized. The compounds were characterized by FTIR, NMR (H-1, C-13) GC-MS and elemental analyses. They were also both modelled by DFT calculations as the crystal structure of 1,3-bis(acetamide)imidazol-3-ium bromide was determined by XRD which is an orthorhombic system with space group P2(1)2(1)2. The structural analyses in gas phase were realized by comparing the experimental NMR and IR spectra with those of the theoretical calculations. In vitro biological activities of the molecules were determined and found that one of them exhibits significant cytotoxic activity. (C) 2017 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2017.02.022
dc.identifier.endpage270en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85012009574en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage263en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.02.022
dc.identifier.urihttps://hdl.handle.net/20.500.14551/21756
dc.identifier.volume1136en_US
dc.identifier.wosWOS:000397375800027en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal Of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectImidazoleen_US
dc.subjectCarbeneen_US
dc.subjectXRDen_US
dc.subjectDensity Functional Theoryen_US
dc.subjectAntibacterialen_US
dc.subjectCytotoxicityen_US
dc.subjectFt-Iren_US
dc.subjectComplexesen_US
dc.subjectDften_US
dc.subjectGenerationen_US
dc.subjectSilver(I)en_US
dc.titleSynthesis and characterization of new N-heterocyclic carbene ligands: 1,3-Bis(acetamide)imidazol-3-ium bromide and 3-(acetamide)-1-(3-aminopropy1)-1H-imidazol-3-ium bromideen_US
dc.typeArticleen_US

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