Syntheses, Spectroscopic, and Thermal Characterization of Cu(II), Ni(II), and Pt(II) Complexes of Some Tridentate Ligands

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dc.authoridKARABULUT, H R Ferhat/0000-0002-9501-6296;
dc.authorwosidTurkyilmaz, Murat/AAK-7876-2020
dc.authorwosidKARABULUT, H R Ferhat/AAA-1402-2021
dc.authorwosidBaran, Yakup/N-4678-2015
dc.contributor.authorTurkyilmaz, Murat
dc.contributor.authorKarabulut, Ferhat
dc.contributor.authorAltun, Ozlen
dc.contributor.authorBaran, Yakup
dc.date.accessioned2024-06-12T10:54:07Z
dc.date.available2024-06-12T10:54:07Z
dc.date.issued2013
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe study emphasized azomethine coordination compounds of Pt(II), Cu(II), and Ni(II) having tetracoordinate geometry around the metal ions with the general formula, [MLCl]Cl, where L, azomethine have been isolated in the solid state. All the ligands were identified by spectroscopic methods and elemental analysis. The synthesized coordination compounds have been characterized by FTIR, magnetic measurements, elemental analysis, electrical conductance, and thermal analysis. Square planar structures have been proposed for the Ni(II) and Pt(II) complexes. Magnetic susceptibility measurements and electronic spectra of the complexes sustain the proposed square planer structures. The complexes thermally stable and this thermal stability is discussed in terms of ligands donor atoms, geometry and central metal ions. Azomethine complexes have a similar thermal behavior for the selected metal ions. The TG analyses suggest high thermal stability for most complexes followed by thermal decomposition in different steps. The decomposition processes were observed as water elimination, chloride anion removal, and degradation of the organic ligands. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.en_US
dc.description.sponsorshipTrakya University TBAP [2011-113]en_US
dc.description.sponsorshipThe authors thank the Trakya University TBAP 2011-113 for the financial support.en_US
dc.identifier.doi10.1080/15533174.2012.757746
dc.identifier.endpage1273en_US
dc.identifier.issn1553-3174
dc.identifier.issue9en_US
dc.identifier.startpage1267en_US
dc.identifier.urihttps://doi.org/10.1080/15533174.2012.757746
dc.identifier.urihttps://hdl.handle.net/20.500.14551/18935
dc.identifier.volume43en_US
dc.identifier.wosWOS:000321888400008en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthesis And Reactivity In Inorganic Metal-Organic And Nano-Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAzomethineen_US
dc.subjectComplexesen_US
dc.subjectMetal Ionsen_US
dc.subjectTG-DTAen_US
dc.subjectThermal Stabilityen_US
dc.subjectTridentateen_US
dc.subjectAsymmetric Transfer Hydrogenationen_US
dc.subjectSchiff-Base Complexesen_US
dc.subjectSpectral Characterizationen_US
dc.subject2nd-Harmonic Generationen_US
dc.subjectInorganic Chromophoresen_US
dc.subjectAmino-Acidsen_US
dc.subjectCopper(Ii)en_US
dc.subjectCatalystsen_US
dc.subjectKetonesen_US
dc.subjectOrganotin(Iv)en_US
dc.titleSyntheses, Spectroscopic, and Thermal Characterization of Cu(II), Ni(II), and Pt(II) Complexes of Some Tridentate Ligandsen_US
dc.typeArticleen_US

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