Structure, Spectroscopic, Magnetic, Fluorescence, and Thermal Studies of Bis(perchlorate)tetrakis(pyrazole)copper(II)

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dc.authorwosidBaran, Yakup/N-4678-2015
dc.authorwosidTurkyilmaz, Murat/AAK-7876-2020
dc.contributor.authorBaran, Yakup
dc.contributor.authorEsener, Hasan
dc.contributor.authorTurkyilmaz, Murat
dc.date.accessioned2024-06-12T10:58:33Z
dc.date.available2024-06-12T10:58:33Z
dc.date.issued2011
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe complex bis(perchlorate) tetrakis(pyrazole) copper(II) has been prepared and characterized by single crystal X-ray analysis, FT-IR, UV-VIS spectroscopy and thermal methods. [Cu(ClO4)(2)(pyzl)(4)] crystallizes in the monoclinic system, space group C2/c, with a = 14.5186(11), b = 9.9513(7), c = 15.8564(11) angstrom, beta = 115.5290(10)degrees V = 2067.2(3)angstrom(3) and z = 4. The molecular and crystal structure are stabilized by inter and intramolecular hydrogen bonds. The complex formation kinetics was studied at 310 nm. The activation parameters of the complex formation kinetics were determined as, Delta H-#: 200 kJ/mol, Delta S-#: 268 J/K. mol. The FT-IR spectra has been measured and assigned in the range of 4000-400 cm(-1). The Cl-O and N-H stretching vibrations confirms the presence of intramolecular hydrogen bonds. The magnetic moment of the complex was found to be 1.73 BM. The fluorescence quenching of pyrazole by Copper(II) was also studied in methanol.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey's research program [1001]; [104T389]en_US
dc.description.sponsorshipFinancial support received from the Scientific and Technological Research Council of Turkey's research program 1001. Grant for 104T389 is gratefully acknowledged. The authors would like to thank Dr. Ismet Kaya for performing thermal analysis.en_US
dc.identifier.doi10.1080/15533174.2011.568466
dc.identifier.endpage715en_US
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-79960678953en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage710en_US
dc.identifier.urihttps://doi.org/10.1080/15533174.2011.568466
dc.identifier.urihttps://hdl.handle.net/20.500.14551/20091
dc.identifier.volume41en_US
dc.identifier.wosWOS:000296318500023en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthesis And Reactivity In Inorganic Metal-Organic And Nano-Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCopper(II)en_US
dc.subjectMagnetic Susceptibilityen_US
dc.subjectFTIRen_US
dc.subjectPyrazoleen_US
dc.subjectStructureen_US
dc.subjectTGAen_US
dc.subjectX-Rayen_US
dc.subjectPyrazole-Derived Ligandsen_US
dc.subjectCoordination Chemistryen_US
dc.subjectComplexesen_US
dc.subjectCrystalen_US
dc.titleStructure, Spectroscopic, Magnetic, Fluorescence, and Thermal Studies of Bis(perchlorate)tetrakis(pyrazole)copper(II)en_US
dc.typeArticleen_US

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