Adsorption of Fe, Mn, Cu and Cr on montmorillonite modified with tributyl phosphate

Küçük Resim Yok

Tarih

2007

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Parlar Scientific Publications (P S P)

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

A simple preconcentration method is described for the determination of Fe, Mn, Cu and Cr in water samples by flame atomic absorption spectrometry. Montmorillonite by the addition of tributyl phosphate was used as adsorbent for column studies. The influences of aqueous solution pH, amount of montmorillonite, as well as flow-rates of adsorption and elution of sample solutions were studied. The present method was found to be applicable to preconcentrate Fe, Mn, Cu and Cr in natural water samples with good results (R.S.D. 3-8%, N=10). The detection limits for Fe, Mn, Cu and Cr were found to be 0.09, 0.23, 0.16 and 0.19 mu g/l; respectively. The adsorption capacities for Fe, Mn, Cu and Cr were calculated to be 14.5, 10.4, 16.0 and 13.6 mg/g, respectively.

Açıklama

Anahtar Kelimeler

Montmorillonite, Water Samples, Flame AAS, Adsorption, Aqueous-Solution, Metal-Ions, Preconcentration, Bentonite, Sorption, Trioctylamine, Silica

Kaynak

Fresenius Environmental Bulletin

WoS Q Değeri

Q4

Scopus Q Değeri

Cilt

16

Sayı

1

Künye