Synthesis, spectroscopic and thermal properties of Pt(II) complexes of some polydentate ligands

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dc.authoridKaya, İsmet/0000-0002-9813-2962;
dc.authorwosidKaya, İsmet/ABD-2324-2020
dc.authorwosidBaran, Yakup/N-4678-2015
dc.authorwosidTurkyilmaz, Murat/AAK-7876-2020
dc.contributor.authorBaran, Yakup
dc.contributor.authorKaya, Ismet
dc.contributor.authorTurkyilmaz, Murat
dc.date.accessioned2024-06-12T11:13:06Z
dc.date.available2024-06-12T11:13:06Z
dc.date.issued2012
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe new tetradentate symmetrical (2R, 2'S)1,1'-piperazine-1,4-diyldipropane-2-thiol) (L-1), (2S)-1-[bis (2-aminoethyl) amino] propan-2-ol) (L-2), and 2-{(E)-[((1R, 2S)-2-{[(1Z)-(2-hydroxy phenyl)methylene]amino}cyclohexyl) imino] methyl} phenol (L-3) ligands were synthesized and characterized on the basis of FT-IR, H-1, C-13 NMR, EI mass, and elemental analysis. Three commercially available ligands, (2,2'-[ethane-1,2-diylbis(thio)] diethanol (L-4), 2,2'-dithiodiethanenamine (L-5), and (2,2-[ethane-1,2-diyldi(imino)] diethanol (L-6), were also studied. Pt(II) complexes were characterized by FTIR, elemental analysis and thermal methods. Thermal behaviors of these complexes were investigated in the range 10-1000 degrees C. Magnetic properties were also studied, and the all complexes were found to be diamagnetic. The structures consist of the monomeric units in which the Pt(II) atoms exhibit square planar geometry. N,N'-bis(salicylidene)-1,2-cyclohexane has been synthesized and characterized by X-ray single crystal diffraction measurement. The ligand crystallizes in monoclinic crystal system and space group, Cc.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [104T389]en_US
dc.description.sponsorshipThe authors wish to thank the Scientific and Technological Research Council of Turkey (TUBITAK) for financial support (project no: 104T389) and BAP. Scientific Research Project of COMU.en_US
dc.identifier.doi10.1007/s10973-011-1567-9
dc.identifier.endpage875en_US
dc.identifier.issn1388-6150
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85027942417en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage869en_US
dc.identifier.urihttps://doi.org/10.1007/s10973-011-1567-9
dc.identifier.urihttps://hdl.handle.net/20.500.14551/23422
dc.identifier.volume107en_US
dc.identifier.wosWOS:000302703400002en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of Thermal Analysis And Calorimetryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPt(II)en_US
dc.subjectPolydentateen_US
dc.subjectFTIRen_US
dc.subjectTGen_US
dc.subjectNMRen_US
dc.subjectThermal Stabilityen_US
dc.subjectX-Rayen_US
dc.subjectSchiff-Basesen_US
dc.subjectPhotochromismen_US
dc.subjectCopper(Ii)en_US
dc.subjectRedoxen_US
dc.titleSynthesis, spectroscopic and thermal properties of Pt(II) complexes of some polydentate ligandsen_US
dc.typeArticleen_US

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