Nonisocyanate polyurethane/silica hybrid coatings via a sol-gel route
Küçük Resim Yok
Tarih
2012
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-Hindawi
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Polyurethane/silica hybrids by a nonisocyanate route were prepared by reacting cyclic carbonate-modified bis(4-glycidyloxy phenyl)phenyl phosphine oxide (BGPPO), and poly(propyleneglycol)diglycidyl ether (PPG-DGE) with hexamethylene diamine. The incorporation of silica was achieved via a solgel method. The effect of silica and phosphine oxide moiety on polyurethane coating properties was studied by physical, mechanical, and thermal tests. Modulus and hardness of the coatings were enhanced by increasing the amount of silica and phosphine oxide based resin. The improvement in flame retardancy and thermal stability of nanocomposites was proved with increased char yield values and decomposition temperatures in thermogravimetric analyses. (C) 2011 Wiley Periodicals, Inc. Adv Polym Techn 31: 390400, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/adv.20262
Açıklama
Anahtar Kelimeler
Nonisocyanate Route, Organic-Inorganic Hybrid, Phosphine Oxide, Polyurethane, Sol-Gel, Phosphorus-Containing Epoxy, Flame-Retardant, Phosphine Oxide, Silicon, Resins, Nanocomposites
Kaynak
Advances In Polymer Technology
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
31
Sayı
4