EXPERIMENTAL AND THEORETICAL ANALYSIS OF N,N?-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE)) BIS(1-(THIOPHEN-2-YL)METHANIMINE) AND N,N?-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE))BIS(1-(4-METHYLTHIOPHEN-2-YL)METHANIMINE) SCHIFF BASE LIGANDS

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dc.authoridUluçam, Gühergül/0000-0001-6481-8483
dc.authorwosidUluçam, Gühergül/AAH-2862-2019
dc.contributor.authorUlucam, Guhergul
dc.contributor.authorYenturk, Busra
dc.date.accessioned2024-06-12T11:16:15Z
dc.date.available2024-06-12T11:16:15Z
dc.date.issued2019
dc.departmentTrakya Üniversitesien_US
dc.description.abstractN,N'-(ethane- 1,2-diyIbis(4,1-phenylene))bis(1-(thiophen-2-yl)methan i mine) and N,N'-(ethane-1,2-diyIbis(4,1-phenylene))bis(1-(4-methylthiophen-2-yl) methanimine) ligands are formed by diamine and two aromatic aldehyde using Schiff base condensation method. Ligands are characterised by fourier transform infrared spectroscopy (FT-IR), H-1- and C-13- nuclear magnetic resonance spectroscopy (H-1- and C-13- NMR) and mass spectroscopy (LC ESVMS) methods. Furthermore. geometric properties such as bond lenghts, bond angles, dihedral angles, electronic properties, highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies are calculated by using Gaussian 09w program. Experimental and theoretical spectrum datas are compared.en_US
dc.description.sponsorshipResearch Fund of Trakya University [TUBAP-2016/22]en_US
dc.description.sponsorshipThe authors acknowledge financial support from Research Fund of Trakya University with the project TUBAP-2016/22.en_US
dc.identifier.doi10.4067/s0717-97072019000104345
dc.identifier.endpage4351en_US
dc.identifier.issn0717-9707
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85067612230en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage4345en_US
dc.identifier.urihttps://doi.org/10.4067/s0717-97072019000104345
dc.identifier.urihttps://hdl.handle.net/20.500.14551/24257
dc.identifier.volume64en_US
dc.identifier.wosWOS:000463996000012en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSoc Chilena Quimicaen_US
dc.relation.ispartofJournal Of The Chilean Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectThiopheneen_US
dc.subjectSchiff Baseen_US
dc.subjectGaussian 09wen_US
dc.subjectDFT/B3LYPen_US
dc.subjectNonlinear-Optical Propertiesen_US
dc.subjectAb-Initioen_US
dc.subjectBiological-Activityen_US
dc.subjectCrystal-Structureen_US
dc.subjectFt-Ramanen_US
dc.subjectComplexesen_US
dc.titleEXPERIMENTAL AND THEORETICAL ANALYSIS OF N,N?-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE)) BIS(1-(THIOPHEN-2-YL)METHANIMINE) AND N,N?-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE))BIS(1-(4-METHYLTHIOPHEN-2-YL)METHANIMINE) SCHIFF BASE LIGANDSen_US
dc.typeArticleen_US

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