A novel cationic Gemini surfactant with amide group: synthesis and micellization behavior in aqueous solutions

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dc.contributor.authorAkbas, Halide
dc.contributor.authorKocaoglu, Semra
dc.contributor.authorBoz, Mesut
dc.contributor.authorDikmen, Alper
dc.date.accessioned2024-06-12T10:55:57Z
dc.date.available2024-06-12T10:55:57Z
dc.date.issued2016
dc.departmentTrakya Üniversitesien_US
dc.description.abstractNovel cationic Gemini surfactant with amide group, N (1),N (10)-bis(3-dodecanamidopropyl)-N (1),N (1),N (10),N (10)-tetramethyldecan-1,10-diammonium bromide (abbreviated as 2C(12)enAm) has been synthesized by two-step reactions, purified and characterized in our laboratory. The critical micelle concentration (CMC) values of this Gemini surfactant were determined using electrical conductivity and surface tension measurements in the range of temperatures from 298.15 to 328.15 K. It was observed that the CMC value of Gemini surfactant has a much lower value compared with monomeric ones and shows a slight increase with an increase in the temperature. The interactions between Gemini and conventional monomeric surfactant hexadecyltrimethylammonium bromide (CTAB) have been studied using the conductivity at a certain micellar concentration and temperature range. Rubingh's theory is used to evaluate the micellar interaction parameters (beta) for the mixed systems. It has been observed that mixed micelle formation in all the binary mixtures exhibited negative synergism (antagonism) or ideal behavior due to positive beta values. Thermodynamics parameters were also obtained from the temperature dependence of the CMC values. From the surface tension measurements, CMC, maximum surface excess concentration at the solution/air interface (I(max)), minimum area per surfactant molecule (A (min)), the surface pressure at CMC (I (CMC)), the surfactant concentration required to reduce the surface tension of solvent by 20 mN m(-1) (pC(20)), and thermodynamic parameters have been evaluated at same temperatures.en_US
dc.description.sponsorshipScientific Research Fund of Trakya University [TUBAP-2011/43]en_US
dc.description.sponsorshipThis work is supported by The Scientific Research Fund of Trakya University (Project No: TUBAP-2011/43).en_US
dc.identifier.doi10.1007/s00396-016-3905-8
dc.identifier.endpage1451en_US
dc.identifier.issn0303-402X
dc.identifier.issn1435-1536
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-84975129807en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1439en_US
dc.identifier.urihttps://doi.org/10.1007/s00396-016-3905-8
dc.identifier.urihttps://hdl.handle.net/20.500.14551/19606
dc.identifier.volume294en_US
dc.identifier.wosWOS:000382149500006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofColloid And Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCationic Gemini Surfactant With Amide Groupen_US
dc.subjectCritical Micelle Concentrationen_US
dc.subjectInteraction Parametersen_US
dc.subjectNegative Synergismen_US
dc.subjectSurface-Active Propertiesen_US
dc.subjectReactive Orange 16en_US
dc.subjectAggregation Behavioren_US
dc.subjectNonionic Surfactantsen_US
dc.subjectIonic Liquidsen_US
dc.subjectChainen_US
dc.subjectElectrolytesen_US
dc.subjectTemperatureen_US
dc.subjectMixturesen_US
dc.subjectPropertyen_US
dc.subjectBromideen_US
dc.titleA novel cationic Gemini surfactant with amide group: synthesis and micellization behavior in aqueous solutionsen_US
dc.typeArticleen_US

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